Looking Good, Feeling Bad; or, What's the Problem with Perc? (2,4,9) The vapor pressure for benzyl chloride is 1.20 mm Hg at 25 °C, and it has a log octanol/water partition Emergency Planning and Community Right-to-Know Act (42 U.S.C. Benzyl chloride | C6H5CH2Cl or C7H7Cl | CID 7503 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. In IUPAC nomenclature the prefix benzyl refers to a C6H5CH2 substituent, for example benzyl chloride or benzyl benzoate. jcamp-dx.js and Khim. Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. Hazardous materials placards (DOT placards) are required when shipping hazardous materials in the United States, Canada and Mexico. The reaction proceeds by the free radical process, involving the intermediacy of free chlorine atoms. Molar mass calculations are explained and there is a JavaScript calculator to aid calculations. CopyCopied, CSID:13840690, http://www.chemspider.com/Chemical-Structure.13840690.html (accessed 08:18, Nov 12, 2020) Some chemicals listed in this database or not pure chemical compounds, rather they are mixtures/solutions of chemicals. Institute of Standards and Technology, nor is it intended to imply To ensure regulatory compliance when transporting hazardous materials or dangerous goods, one must receive proper training and certification from a qualified instructor and refer to the current year's Code of Federal Regulations Title 49 (49CFR) or your country's shipping regulations. All Rights Reserved. A member of the class of benzyl chlorides that is toluene substituted on the alpha-carbon with chlorine. In contact with mucous membranes, hydrolysis produces hydrochloric acid. Benzyl ethers are often derived from benzyl chloride. click the mouse on the plot to revert to the orginal display. ; Lee, D.W.; Heo, G.S., Determination of volatile organic compounds (VOCs) using tedlar bag/solid-phase microextraction/gas chromatography/mass spectrometry (SPME/GC/MS) in ambient and workplace air, Bull. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), NIST Mass Spectrometry Data Center, William E. Wallace, director, Modified by NIST for use in this application. (e.g., Sadtler Research Labs Under US-EPA Contract. Database and to verify that the data contained therein have Use a separatory funnel to remove the aqueous layer. Except where otherwise noted, data are given for materials in their. Benzyltri-n-butylammonium chloride. Sorry we cannot compare more than 4 products at a time. More info. Data Program, but require an annual fee to access. One SM user made benzyl chloride by dissolving chlorine gas in toluene, then added a small amount of lithium bromide. This table can be sorted by proper shipping name, UN/NA ID and/or by primary hazard class/division. Use or mention of technologies or programs in this web site is not [5] It is preferable over benzyl bromide for the preparation of this reagent, since the reaction of the bromide with magnesium tends to form the Wurtz coupling product 1,2-diphenylethane. Molecular Weight: 531.13. Benzyl chloride also reacts readily with metallic magnesium in water-free conditions, to produce a Grignard reagent, extremely useful for the synthesis of various compounds containing an aromatic ring. Benzyl chloride is classified as List II drug precursor chemical in most countries, in the US being classified as DEA List II chemical. Benzoic acid (C6H5COOH) can be prepared by oxidation of benzyl chloride in the presence of alkaline KMnO4: Benzyl chloride may be used in the synthesis of amphetamine-class drugs, and for this reason, sales of benzyl chloride are monitored as a List II drug precursor chemical by the US Drug Enforcement Administration. hydrochloric acid. Light is needed to initiate the reaction, but once it starts, there's no need to further expose the flask to strong light, unless your goal is to continue the reaction.

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